Nuclear inelastic scattering of synchrotron radiation has been used now since 10 years as a tool for vibrational spectroscopy. This method has turned out especially useful in case of large molecules that contain a Mössbauer active metal center. Recent applications to iron–sulfur proteins, to iron(II) spin crossover complexes and to tin-DNA complexes are discussed. Special emphasis is given to the combination of nuclear inelastic scattering and density functional calculations.
HPAULSEN, PWEGNER, HWINKLER, JAWOLNY, LHBOETTGER, AXTRAUTWEIN, et al. (2005). Dynamics of metal centers monitored by nuclear inelastic scattering. HYPERFINE INTERACTIONS, 165(1-4), 17-24 [10.1007/s10751-006-9242-4].
Dynamics of metal centers monitored by nuclear inelastic scattering
SILVESTRI, Arturo;LA MANNA, Gianfranco;
2005-01-01
Abstract
Nuclear inelastic scattering of synchrotron radiation has been used now since 10 years as a tool for vibrational spectroscopy. This method has turned out especially useful in case of large molecules that contain a Mössbauer active metal center. Recent applications to iron–sulfur proteins, to iron(II) spin crossover complexes and to tin-DNA complexes are discussed. Special emphasis is given to the combination of nuclear inelastic scattering and density functional calculations.
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