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01 - Contributo in rivista: [74577] Home page macrotipologia

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Prodotti recenti

Targeting non-canonical DNA with π-extended Schiff Base complexes of Zinc(II), Copper(II), and Nickel(II): Insights into G-Quadruplex binding modes

The selective recognition of G-quadruplex (G4) DNA structures by metal complexes holds considerable promise for anticancer drug development, particularly for targeting oncogene promoters and telomeric regions. Herein, we report the synthesis, structural characterization, and DNA-binding strength evaluation of a new series of transition metal complexes derived from a N4 tetradentate naphthalene-bridged Schiff base ligand (Naphthim). The zinc(II), copper(II) and nickel(II) complexes were obtain...

Synthesis and binding studies of two new coumarin-squaramide-based receptors for NSAIDs

Two new squaramide-based receptors containing coumarin units have been synthesized and characterized in both solution and solid states. L1 (3-(benzylamino)-4-((2-oxo-4-(trifluoromethyl)-2H-chromen-7-yl)amino)cyclobut-3-ene-1,2-dione) is a linear molecule, while L2 (4,4′-((1,3-phenylenebis(methylene))bis(azanediyl))bis(3-((2-oxo-4-(trifluoromethyl)-2H-chromen-7-yl)amino)cyclobut-3-ene-1,2-dione)) is an open chain ligand which results in the ditopic form of the simpler parent ligand L1. The new...

Biagio Bartalini’s Herbarium: an insight into the flora of Siena and its surroundings (Italy) during the eighteenth century

Studying historical herbaria is invaluable for botanical research. This work analysed Biagio Bartalini's Herbarium, a late eighteenth-century multi-taxon collection from Siena and its surroundings (central Italy). We revised taxonomic identifications, updated nomenclature, digitised associated information, created a high-resolution photographic database, and uploaded the dataset on the Global Biodiversity Information Facility (GBIF) portal. The Herbarium includes 676 specimens of 588 species ...

Ionic liquid-based antioxidant materials: a bird's eye view on the most recent literature

The unwanted effects of radicals formed in some oxidation processes have propelled the obtainment of protecting antioxidant materials for packaging or coatings. A recent development in this regard is constituted by ionic liquid (IL)-based antioxidant materials. This brief perspective surveys the literature and discusses works that appeared in the last decade on such topics. The discussion is divided into two sections: polymer composites and gel-based materials. The latter section also include...

Genetic structure and connectivity of the critically endangered deep-sea octocoral Isidella elongata: implications for marine biodiversity conservation in the Mediterranean Sea

The protection of the Vulnerable Marine Ecosystem identified by the presence of the critically endangered bamboo coral Isidella elongata has been recognized as an urgent task. Although some research has focused on the spatial distribution of this species, there is no information available on its connectivity and genetic structure. This is the first study to examine the genetic diversity pattern and inter-population connectivity of I. elongata at the Mediterranean scale. The DNA-based approach...

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