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EnglishTwo polystyrene-supported and six homogeneous MacMillan imidazolidinone catalysts were prepared and tested for the asymmetric a-alkylation of propanal with benzodithiolylium tetrafluoroborate. The chiral imidazolidinone was linked to polystyrene through the N-3 atom or through the phenyl ring and their catalytic activity was compared with that of their unsupported precursors. This comparison has allowed us to find an unsupported catalyst that displays high catalytic activity down to 5 or 2 mol% at room temperature with a high level of enantioselectivity also when used with hexanal and 3-phenylpropanal. In addition, one of the heterogeneous materials was revealed to be highly recyclable for at least eight cycles with no loss in efficiency working at the same levels of activity and enantioselectivity as the unsupported counterpart.
| Data di pubblicazione: | 2014 |
| Titolo: | Recyclable Heterogeneous and Low-Loading Homogeneous Chiral Imidazolidinone Catalysts for alpha-Alkylation of Aldehydes |
| Autori: | |
| Citazione: | Salvo, A., Giacalone, F., Noto, R., & Gruttadauria, M. (2014). Recyclable Heterogeneous and Low-Loading Homogeneous Chiral Imidazolidinone Catalysts for alpha-Alkylation of Aldehydes. CHEMPLUSCHEM, 79, 857-862. |
| Rivista: | |
| Digital Object Identifier (DOI): | 10.1002/cplu.201400030 |
| Abstract: | Two polystyrene-supported and six homogeneous MacMillan imidazolidinone catalysts were prepared and tested for the asymmetric a-alkylation of propanal with benzodithiolylium tetrafluoroborate. The chiral imidazolidinone was linked to polystyrene through the N-3 atom or through the phenyl ring and their catalytic activity was compared with that of their unsupported precursors. This comparison has allowed us to find an unsupported catalyst that displays high catalytic activity down to 5 or 2 mol% at room temperature with a high level of enantioselectivity also when used with hexanal and 3-phenylpropanal. In addition, one of the heterogeneous materials was revealed to be highly recyclable for at least eight cycles with no loss in efficiency working at the same levels of activity and enantioselectivity as the unsupported counterpart. |
| URL: | http://onlinelibrary.wiley.com/doi/10.1002/cplu.201400030/abstract |
| Settore Scientifico Disciplinare: | Settore CHIM/06 - Chimica Organica |
| Appare nelle tipologie: | 1.01 Articolo in rivista |
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|---|---|---|---|---|
| ChemPlusChem 2014, 79, 857-862.pdf | Articolo principale | N/A | Administrator Richiedi una copia |
http://hdl.handle.net/10447/96166
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