The photochemical version of the Boulton–Katritzky reaction has been studied, examining the behaviour of the arylhydrazones of 3-benzoyl-5-X-1,2,4-oxadiazoles. The effect of several modifications of the substrates structure (the E and/or Z structures of arylhydrazones, the possible presence of substituents in the arylhydrazono moiety, and the nature of substituents at C-5 of the 1,2,4-oxadiazole ring) on the course of the photochemical rearrangement has been examined.
D'Auria, M., Frenna, V., Marullo, S., Raccioppi, R., Spinelli, D., Viggiani, L. (2012). Photochemical isomerization of aryl hydrazones of 1,2,4-oxadiazole derivatives into the corresponding triazoles. PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 11, 1383-1388 [10.1039/C2PP25073J].
Photochemical isomerization of aryl hydrazones of 1,2,4-oxadiazole derivatives into the corresponding triazoles
FRENNA, Vincenzo;MARULLO, Salvatore;
2012-01-01
Abstract
The photochemical version of the Boulton–Katritzky reaction has been studied, examining the behaviour of the arylhydrazones of 3-benzoyl-5-X-1,2,4-oxadiazoles. The effect of several modifications of the substrates structure (the E and/or Z structures of arylhydrazones, the possible presence of substituents in the arylhydrazono moiety, and the nature of substituents at C-5 of the 1,2,4-oxadiazole ring) on the course of the photochemical rearrangement has been examined.File | Dimensione | Formato | |
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