We demonstrate that halogen bonding strongly enhances the nonlinear optical response of poled supramolecular polymer systems. We compare three nonlinear optical chromophores with similar electronic structures but different bond-donating units, and show that both the type and the strength of the noncovalent interaction between the chromophores and the polymer matrix play their own distinctive roles in the optical nonlinearity of the systems.
Virkki M., Tuominen O., Forni A., Saccone M., Metrangolo P., Resnati G., et al. (2015). Halogen bonding enhances nonlinear optical response in poled supramolecular polymers. JOURNAL OF MATERIALS CHEMISTRY. C, 3(13), 3003-3006 [10.1039/c5tc00484e].
Data di pubblicazione: | 2015 | |
Titolo: | Halogen bonding enhances nonlinear optical response in poled supramolecular polymers | |
Autori: | ||
Citazione: | Virkki M., Tuominen O., Forni A., Saccone M., Metrangolo P., Resnati G., et al. (2015). Halogen bonding enhances nonlinear optical response in poled supramolecular polymers. JOURNAL OF MATERIALS CHEMISTRY. C, 3(13), 3003-3006 [10.1039/c5tc00484e]. | |
Rivista: | ||
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/c5tc00484e | |
Abstract: | We demonstrate that halogen bonding strongly enhances the nonlinear optical response of poled supramolecular polymer systems. We compare three nonlinear optical chromophores with similar electronic structures but different bond-donating units, and show that both the type and the strength of the noncovalent interaction between the chromophores and the polymer matrix play their own distinctive roles in the optical nonlinearity of the systems. | |
URL: | http://pubs.rsc.org/en/journals/journalissues/tc | |
Settore Scientifico Disciplinare: | Settore CHIM/07 - Fondamenti Chimici Delle Tecnologie | |
Appare nelle tipologie: | 1.01 Articolo in rivista |
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