La1-xSrxCr1-yFeyO3-δ (x=0, 0.1, 0.15, 0.2; y=0, 0.3, 0.5) perovskite-type oxide powders were synthesized by solution combustion synthesis and characterized by X-ray diffraction, X-ray photoelectron spectroscopy and H2-temperature programmed reduction. Selected compositions were studied by CH4-temperature programmed reduction in the absence and in the presence of H2S. Temperature programmed oxidation and structural characterizations were performed in order to discriminate the nature of residual deposits on the catalyst surface. The study about reduction in different based-methane mixture revealed that total and partial methane oxidation occurred in the range ∼450-1000°C independently of methane concentration. The H2S influence on methane oxidation was evaluated and experiments in CH4/H2S gas mixture indicated that La0.9Sr0.1Cr0.7Fe0.3O3-δ oxidized CH4 to CO2 and CO, as well as H2S to SO2. La0.9Sr0.1Cr0.7Fe0.3O3-δ was therefore identified a potential anode material for Intermediate Temperature - Solid Oxide Fuel Cells directly fed with CH4 in the presence of H2S.

Aliotta C, Liotta LF, Deganello F, La Parola V, Martorana A (2016). Direct Methane Oxidation on La1-xSrxCr1-yFeyO3-δ perovskite-type oxides as Potential Anode for Intermediate Temperature Solid Oxide Fuel Cells. APPLIED CATALYSIS. B, ENVIRONMENTAL, 180, 424-433 [10.1016/j.apcatb.2015.06.012].

Direct Methane Oxidation on La1-xSrxCr1-yFeyO3-δ perovskite-type oxides as Potential Anode for Intermediate Temperature Solid Oxide Fuel Cells

ALIOTTA, Chiara
;
MARTORANA, Antonino
2016-01-01

Abstract

La1-xSrxCr1-yFeyO3-δ (x=0, 0.1, 0.15, 0.2; y=0, 0.3, 0.5) perovskite-type oxide powders were synthesized by solution combustion synthesis and characterized by X-ray diffraction, X-ray photoelectron spectroscopy and H2-temperature programmed reduction. Selected compositions were studied by CH4-temperature programmed reduction in the absence and in the presence of H2S. Temperature programmed oxidation and structural characterizations were performed in order to discriminate the nature of residual deposits on the catalyst surface. The study about reduction in different based-methane mixture revealed that total and partial methane oxidation occurred in the range ∼450-1000°C independently of methane concentration. The H2S influence on methane oxidation was evaluated and experiments in CH4/H2S gas mixture indicated that La0.9Sr0.1Cr0.7Fe0.3O3-δ oxidized CH4 to CO2 and CO, as well as H2S to SO2. La0.9Sr0.1Cr0.7Fe0.3O3-δ was therefore identified a potential anode material for Intermediate Temperature - Solid Oxide Fuel Cells directly fed with CH4 in the presence of H2S.
2016
Settore CHIM/03 - Chimica Generale E Inorganica
Aliotta C, Liotta LF, Deganello F, La Parola V, Martorana A (2016). Direct Methane Oxidation on La1-xSrxCr1-yFeyO3-δ perovskite-type oxides as Potential Anode for Intermediate Temperature Solid Oxide Fuel Cells. APPLIED CATALYSIS. B, ENVIRONMENTAL, 180, 424-433 [10.1016/j.apcatb.2015.06.012].
File in questo prodotto:
File Dimensione Formato  
1-s2.0-S0926337315003392-main.pdf

Solo gestori archvio

Descrizione: Articolo principale
Tipologia: Versione Editoriale
Dimensione 1.54 MB
Formato Adobe PDF
1.54 MB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10447/278276
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 42
  • ???jsp.display-item.citation.isi??? 41
social impact