A photochemical, alternative and eco-compatible approach to perfluoroalkyl derivatives of pyrene is presented. The perfluoroalkyl chain is regiospecifically introduced at the 1 position of pyrene. The synthesized products have been embedded in a polymethylmethacrylate matrix by photocuring at 365 nm. Both the photochemical reactions can be considered a “green tool” for the synthetic chemist in order to obtain materials with prospective optoelectronic applications. The so-obtained composites have been the object of a study by UV and fluorescence spectroscopy in order to explore their luminescence properties. The small angle X-ray scattering and the transmission electron microscopy techniques were used to investigate the microstructure. A correlation between the optical and the structural properties is herein presented.
Pibiri, I., Buscemi, S., Palumbo Piccionello, A., Saladino, M.L., Chillura Martino, D., Caponetti E (2014). Photochemical synthesis of pyrene perfluoroalkyl derivatives and their embedding in a polymethylmethacrylate matrix: a spectroscopic and structural study. JOURNAL OF MATERIALS CHEMISTRY, 2(2), 7722-7730 [10.1039/c4tc01187b].
Photochemical synthesis of pyrene perfluoroalkyl derivatives and their embedding in a polymethylmethacrylate matrix: a spectroscopic and structural study
PIBIRI, Ivana;BUSCEMI, Silvestre;PALUMBO PICCIONELLO, Antonio;SALADINO, Maria Luisa;CHILLURA MARTINO, Delia Francesca;CAPONETTI, Eugenio
2014-01-01
Abstract
A photochemical, alternative and eco-compatible approach to perfluoroalkyl derivatives of pyrene is presented. The perfluoroalkyl chain is regiospecifically introduced at the 1 position of pyrene. The synthesized products have been embedded in a polymethylmethacrylate matrix by photocuring at 365 nm. Both the photochemical reactions can be considered a “green tool” for the synthetic chemist in order to obtain materials with prospective optoelectronic applications. The so-obtained composites have been the object of a study by UV and fluorescence spectroscopy in order to explore their luminescence properties. The small angle X-ray scattering and the transmission electron microscopy techniques were used to investigate the microstructure. A correlation between the optical and the structural properties is herein presented.File | Dimensione | Formato | |
---|---|---|---|
2014JmaterchemC.pdf
Solo gestori archvio
Descrizione: Articolo
Dimensione
1.15 MB
Formato
Adobe PDF
|
1.15 MB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.