We have investigated a newly synthesized complex of D-ribonic acid with dimethyltin(IV). The structure of the complex in solution has been characterized by means of 1H, 13C, and 119Sn NMR and by DFT calculations. The comparison of experimental and computational results allowed the determination of the stable conformation in solution as well as the detection of a dimerization process. Moreover, evidence is given of active coordination of the metal by the solvent.

BAGNO A, BERTAZZI N, CASELLA G, PELLERITO L, SAIELLI G, SCIACCA ID (2006). Structure of D-ribonic acid-dimethyltin(IV) in coordinating solvents: an experimental and DFT 119Sn NMR study. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 19(12), 874-883 [10.1002/poc.1041].

Structure of D-ribonic acid-dimethyltin(IV) in coordinating solvents: an experimental and DFT 119Sn NMR study.

BERTAZZI, Nuccio;CASELLA, Girolamo;PELLERITO, Lorenzo;SCIACCA, Ivan Diego
2006-01-01

Abstract

We have investigated a newly synthesized complex of D-ribonic acid with dimethyltin(IV). The structure of the complex in solution has been characterized by means of 1H, 13C, and 119Sn NMR and by DFT calculations. The comparison of experimental and computational results allowed the determination of the stable conformation in solution as well as the detection of a dimerization process. Moreover, evidence is given of active coordination of the metal by the solvent.
https://onlinelibrary.wiley.com/doi/abs/10.1002/poc.1041
BAGNO A, BERTAZZI N, CASELLA G, PELLERITO L, SAIELLI G, SCIACCA ID (2006). Structure of D-ribonic acid-dimethyltin(IV) in coordinating solvents: an experimental and DFT 119Sn NMR study. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 19(12), 874-883 [10.1002/poc.1041].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10447/8509
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