Ultrafast solvent-assisted level crossing in 1-Naphthol

The nonadiabatic inversion dynamics of the energetic order of the electronic excited states of the photoacid 1-naphthol have been revealed by ultrafast spectroscopy on a femtosecond timescale (see picture; IC=internal conversion). The energetic order of the excited states La and Lb of 1-naphthol is reversed in 60 fs in polar dimethyl sulfoxide solvent.

Messina, F., Prémont Schwarz, M., Braem, O., Xiao, D., Batista, V., Nibbering, E., et al. (2013). Ultrafast solvent-assisted level crossing in 1-Naphthol. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 52(27), 6871-6875.

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Data di pubblicazione: 2013
Titolo: Ultrafast solvent-assisted level crossing in 1-Naphthol
Autori: 
MESSINA, Fabrizio
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Citazione: Messina, F., Prémont Schwarz, M., Braem, O., Xiao, D., Batista, V., Nibbering, E., et al. (2013). Ultrafast solvent-assisted level crossing in 1-Naphthol. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 52(27), 6871-6875.
Rivista: 
ANGEWANDTE CHEMIE. INTERNATIONAL EDITION  
Digital Object Identifier (DOI): http://dx.doi.org/10.1002/anie.201301931
Abstract: The nonadiabatic inversion dynamics of the energetic order of the electronic excited states of the photoacid 1-naphthol have been revealed by ultrafast spectroscopy on a femtosecond timescale (see picture; IC=internal conversion). The energetic order of the excited states La and Lb of 1-naphthol is reversed in 60 fs in polar dimethyl sulfoxide solvent.
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http://hdl.handle.net/10447/80665
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