The nonadiabatic inversion dynamics of the energetic order of the electronic excited states of the photoacid 1-naphthol have been revealed by ultrafast spectroscopy on a femtosecond timescale (see picture; IC=internal conversion). The energetic order of the excited states La and Lb of 1-naphthol is reversed in 60 fs in polar dimethyl sulfoxide solvent.
Messina, F., Prémont-Schwarz, M., Braem, O., Xiao, D., Batista VS, Nibbering ETJ, et al. (2013). Ultrafast solvent-assisted level crossing in 1-Naphthol. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 52(27), 6871-6875 [http://dx.doi.org/10.1002/anie.201301931].
Ultrafast solvent-assisted level crossing in 1-Naphthol
MESSINA, Fabrizio;
2013
Abstract
The nonadiabatic inversion dynamics of the energetic order of the electronic excited states of the photoacid 1-naphthol have been revealed by ultrafast spectroscopy on a femtosecond timescale (see picture; IC=internal conversion). The energetic order of the excited states La and Lb of 1-naphthol is reversed in 60 fs in polar dimethyl sulfoxide solvent.
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