The nonadiabatic inversion dynamics of the energetic order of the electronic excited states of the photoacid 1-naphthol have been revealed by ultrafast spectroscopy on a femtosecond timescale (see picture; IC=internal conversion). The energetic order of the excited states La and Lb of 1-naphthol is reversed in 60 fs in polar dimethyl sulfoxide solvent.

Messina, F., Prémont-Schwarz, M., Braem, O., Xiao, D., Batista VS, Nibbering ETJ, et al. (2013). Ultrafast solvent-assisted level crossing in 1-Naphthol. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 52(27), 6871-6875 [http://dx.doi.org/10.1002/anie.201301931].

Ultrafast solvent-assisted level crossing in 1-Naphthol

MESSINA, Fabrizio;
2013

Abstract

The nonadiabatic inversion dynamics of the energetic order of the electronic excited states of the photoacid 1-naphthol have been revealed by ultrafast spectroscopy on a femtosecond timescale (see picture; IC=internal conversion). The energetic order of the excited states La and Lb of 1-naphthol is reversed in 60 fs in polar dimethyl sulfoxide solvent.
Messina, F., Prémont-Schwarz, M., Braem, O., Xiao, D., Batista VS, Nibbering ETJ, et al. (2013). Ultrafast solvent-assisted level crossing in 1-Naphthol. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 52(27), 6871-6875 [http://dx.doi.org/10.1002/anie.201301931].
File in questo prodotto:
File Dimensione Formato  
AngChm2013.pdf

accesso aperto

Dimensione 1.22 MB
Formato Adobe PDF
1.22 MB Adobe PDF Visualizza/Apri

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10447/80665
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 21
  • ???jsp.display-item.citation.isi??? 21
social impact