We rigorously analyze the nonequilibrium thermodynamic behavior of various formulations of quantum Brownian motion using the framework of stochastic thermodynamics. While the widely used Caldeira-Leggett master equation exhibits desirable thermodynamic features—such as the fulfillment of a detailed balance—it fails to ensure complete positivity. In contrast, several completely positive and trace-preserving extensions turn out to be thermodynamically controversial. We show that such extensions introduce anomalous phase-space structures that violate detailed balance at the steady state, leading to nonvanishing entropy production and spurious nonequilibrium currents lacking a clear physical interpretation. Our results highlight a fundamental tension between quantum consistency and thermodynamic equilibration in open quantum systems.
Artini, S., Lo Monaco, G., Imparato, A., Paternostro, M., Donadi, S. (2026). Broken detailed balance and entropy production in completely positive and trace-preserving quantum Brownian motion. PHYSICAL REVIEW RESEARCH, 8(3) [10.1103/qqxn-qc4g].
Broken detailed balance and entropy production in completely positive and trace-preserving quantum Brownian motion
Artini, Simone
Primo
;Lo Monaco, Gabriele;Paternostro, Mauro;
2026-08-21
Abstract
We rigorously analyze the nonequilibrium thermodynamic behavior of various formulations of quantum Brownian motion using the framework of stochastic thermodynamics. While the widely used Caldeira-Leggett master equation exhibits desirable thermodynamic features—such as the fulfillment of a detailed balance—it fails to ensure complete positivity. In contrast, several completely positive and trace-preserving extensions turn out to be thermodynamically controversial. We show that such extensions introduce anomalous phase-space structures that violate detailed balance at the steady state, leading to nonvanishing entropy production and spurious nonequilibrium currents lacking a clear physical interpretation. Our results highlight a fundamental tension between quantum consistency and thermodynamic equilibration in open quantum systems.| File | Dimensione | Formato | |
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