Nutrient Recovery from Zeolite and Biochar Columns: The Case Study of Marineo (Italy) Wastewater Treatment Plant

Rapid population and economic growth have increased the demand for depleting resources. Nitrogen (N) and phosphorus (P) are mineral elements that perform important functions in plants, but their extraction is not sustainable. In addition, these elements contribute significantly to the eutrophication of water bodies. The recovery of these nutrients from wastewater by adsorption techniques offers a promising solution. Previous studies have demonstrated the adsorption capabilities of materials such as zeolite for ammonium (NH4+) and biochar for P. In addition, these materials can serve as a source of N and P for plants in a circular economy context. In this regard, this study aims to evaluate the recovery of N and P by the adsorption capacities of zeolite and biochar through a column test with treated wastewater. Two columns positioned in series, one filled with 2.7 kg of zeolite and the other with 397 g of biochar, were placed at the outlet of the full-scale sewage treatment plant of Marineo (Italy). The zeolite adsorbed 3.6 g of NH4+ accumulated during the test with a rate of adsorption of 44% and adsorption of 1.33 mg g-1 of NH4+. The biochar adsorbed about 11 g of P accumulated during the test, with an adsorption percentage of 13% and an adsorption of 26.75 mg g-1 of P. Despite some problems related to the effluent used during the test, the tested materials showed good adsorption properties.