We studied the emission of the O2 molecules embedded in fumed silica (amorphous silicon dioxide) nanoparticles differing for diameters and specific surface. By using a 1064 nm laser as a source we recorded both the O2 emission and the Raman signal of silica. Our experimental data show that the O2 emission/Raman signal (at 800cm-1) ratio decreases with increasing the specific surface both for the as received and the loaded samples. By performing a thermal treatment (600 °C for 2h) we modified the structure and the water content of the smallest nanoparticles without observing any significant change in the O2 emission/Raman signal ratio. Our data are explained by a shell model showing that the O2 emission is essentially due to the molecules entrapped in the core of the nanoparticles, whereas the contribution due to the surface shell, having a thickness of about 1 nm, is negligible because of its high content of Si-OH groups that introduce non-radiative relaxation channels or because of the very low content of molecules trapped in this thin region.
Alessi, A., Iovino, G., Buscarino, G., Agnello, S., & Gelardi, F. (2013). Entrapping of O2 Molecules in Nanostructured Silica Probed by Photoluminescence. JOURNAL OF PHYSICAL CHEMISTRY. C, 117(6), 2616-2622.
|Data di pubblicazione:||2013|
|Titolo:||Entrapping of O2 Molecules in Nanostructured Silica Probed by Photoluminescence|
|Citazione:||Alessi, A., Iovino, G., Buscarino, G., Agnello, S., & Gelardi, F. (2013). Entrapping of O2 Molecules in Nanostructured Silica Probed by Photoluminescence. JOURNAL OF PHYSICAL CHEMISTRY. C, 117(6), 2616-2622.|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1021/jp310314t|
|Appare nelle tipologie:||1.01 Articolo in rivista|