Selective photocatalytic oxidation of aromatic alcohols to aldehydes was performed in water in the presence of TiO2 rutile photocatalysts that exhibited a low degree of crystallinity. The nanostructured rutile samples, prepared ex TiCl4 at very low temperature, ensured a selectivity toward the aldehyde 3 to 4-fold higher than the commercial rutile tested (Sigma-Aldrich).
YURDAKAL, S., PALMISANO, G., LODDO, V., AUGUGLIARO, V., PALMISANO, L. (2008). Nanostructured Rutile TiO2 for Selective Photocatalytic Oxidation of Aromatic Alcohols to Aldehydes in Water. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130(5), 1568-1569 [10.1021/ja709989e].
Nanostructured Rutile TiO2 for Selective Photocatalytic Oxidation of Aromatic Alcohols to Aldehydes in Water
PALMISANO, Giovanni;LODDO, Vittorio;AUGUGLIARO, Vincenzo;PALMISANO, Leonardo
2008-01-01
Abstract
Selective photocatalytic oxidation of aromatic alcohols to aldehydes was performed in water in the presence of TiO2 rutile photocatalysts that exhibited a low degree of crystallinity. The nanostructured rutile samples, prepared ex TiCl4 at very low temperature, ensured a selectivity toward the aldehyde 3 to 4-fold higher than the commercial rutile tested (Sigma-Aldrich).File | Dimensione | Formato | |
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