Two mononuclear Pd(II) complexes [PdCl2(pfptp)] (1) and [PdCl2(pfhtp)] (2), with ligands 2-(3-perfluoropropyl-1-methyl-1,2,4-triazole-5yl)-pyridine (pfptp) and 2-(3-perfluoroheptyl-1-methyl- 1,2,4-triazole-5yl)-pyridine (pfhtp), were synthesized and structurally characterized. The two complexes showed a bidentate coordination of the ligand occurring through N atom of pyridine ring and N4 atom of 1,2,4-triazole. Both complexes showed antimicrobial activity when tested against both Gram-negative and Gram-positive bacterial strains.
Rubino S., Alduina R., Cancemi P., Girasolo M.A., Di Stefano V., Orecchio S., et al. (2020). Mononuclear perfluoroalkyl-heterocyclic complexes of PD(II): Synthesis, structural characterization and antimicrobial activity. MOLECULES, 25(19), 1-9 [10.3390/molecules25194487].
Mononuclear perfluoroalkyl-heterocyclic complexes of PD(II): Synthesis, structural characterization and antimicrobial activity
Rubino S.
;Alduina R.
;Cancemi P.;Girasolo M. A.;Di Stefano V.;Orecchio S.;Buscemi S.;Pibiri I.
2020-01-01
Abstract
Two mononuclear Pd(II) complexes [PdCl2(pfptp)] (1) and [PdCl2(pfhtp)] (2), with ligands 2-(3-perfluoropropyl-1-methyl-1,2,4-triazole-5yl)-pyridine (pfptp) and 2-(3-perfluoroheptyl-1-methyl- 1,2,4-triazole-5yl)-pyridine (pfhtp), were synthesized and structurally characterized. The two complexes showed a bidentate coordination of the ligand occurring through N atom of pyridine ring and N4 atom of 1,2,4-triazole. Both complexes showed antimicrobial activity when tested against both Gram-negative and Gram-positive bacterial strains.
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