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EnglishA systematic structure-property relationship study on hydrogen-bonded liquid crystals was performed, revealing the impact of resonance-assisted hydrogen bonds (RAHBs) on the self-assembling behavior of the supramolecular architecture. The creation of a six-membered intramolecular hydrogen-bonded ring acts as a counterpart to the self-organization between hydrogen bond donators and acceptors and determines thus the suprastructure. Variation of the hydrogen-bonding pattern allowed us to significantly improve the temperature range of the reported liquid crystalline assemblies.
Saccone M., Pfletscher M., Kather S., Wolper C., Daniliuc C., Mezger M., et al. (2019). Improving the mesomorphic behaviour of supramolecular liquid crystals by resonance-assisted hydrogen bonding. JOURNAL OF MATERIALS CHEMISTRY. C, 7(28), 8643-8648 [10.1039/c9tc02787d].
| Data di pubblicazione: | 2019 | |
| Titolo: | Improving the mesomorphic behaviour of supramolecular liquid crystals by resonance-assisted hydrogen bonding | |
| Autori: | ||
| Citazione: | Saccone M., Pfletscher M., Kather S., Wolper C., Daniliuc C., Mezger M., et al. (2019). Improving the mesomorphic behaviour of supramolecular liquid crystals by resonance-assisted hydrogen bonding. JOURNAL OF MATERIALS CHEMISTRY. C, 7(28), 8643-8648 [10.1039/c9tc02787d]. | |
| Rivista: | ||
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/c9tc02787d | |
| Abstract: | A systematic structure-property relationship study on hydrogen-bonded liquid crystals was performed, revealing the impact of resonance-assisted hydrogen bonds (RAHBs) on the self-assembling behavior of the supramolecular architecture. The creation of a six-membered intramolecular hydrogen-bonded ring acts as a counterpart to the self-organization between hydrogen bond donators and acceptors and determines thus the suprastructure. Variation of the hydrogen-bonding pattern allowed us to significantly improve the temperature range of the reported liquid crystalline assemblies. | |
| URL: | http://pubs.rsc.org/en/journals/journal/tc | |
| Settore Scientifico Disciplinare: | Settore CHIM/07 - Fondamenti Chimici Delle Tecnologie | |
| Appare nelle tipologie: | 1.01 Articolo in rivista |
File in questo prodotto:
| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| Improving the Mesomorphic.pdf | Pre-print | Open Access Visualizza/Apri |
http://hdl.handle.net/10447/398691
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