Two new complexs of Ru(III) with glucosaminic acid and 1-Methyluracil, [RuCl2(Glun-N,O)2]H (I), (Glun-= glucosaminate); [RuCl4(1-MeU-N3)(DMSO)]H2.H2O (II), (1-MeU-= 1-Methyluracilate) were prepared from the same Ru(III) precursors, RuCl3•3H2O and [(DMSO)2H][trans-RuCl4(DMSO)2]. The characterization of the complexes have been carried out by elemental analysis, FT-IR, ES-MS, NMR and EXAFS.
ABBATE M, CATALDO S, FIORE T, PELLERITO C, PRINZIVALLI C, SCOPELLITI M, et al. (2008). Synthesis, Structural characterization and Exafs investigations of new ruthenium(III) complexes. ATTI DELLA ACCADEMIA DI SCIENZE, LETTERE E ARTI DI PALERMO, PARTE PRIMA: SCIENZE, SERIE QUINTA,VOL.XXIV (TOMO I: Scienze), 107-116.
Synthesis, Structural characterization and Exafs investigations of new ruthenium(III) complexes.
ABBATE, Michele;CATALDO, Salvatore;FIORE, Tiziana;PELLERITO, Claudia;PRINZIVALLI, Cristina;SCOPELLITI, Michelangelo;PELLERITO, Lorenzo
2008-01-01
Abstract
Two new complexs of Ru(III) with glucosaminic acid and 1-Methyluracil, [RuCl2(Glun-N,O)2]H (I), (Glun-= glucosaminate); [RuCl4(1-MeU-N3)(DMSO)]H2.H2O (II), (1-MeU-= 1-Methyluracilate) were prepared from the same Ru(III) precursors, RuCl3•3H2O and [(DMSO)2H][trans-RuCl4(DMSO)2]. The characterization of the complexes have been carried out by elemental analysis, FT-IR, ES-MS, NMR and EXAFS.
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