Several new diorganotin(IV) and triorganotin(IV) complexes with 4-amino-3- (4-chloro phenyl)]-butanoic acid ( = Baclofen) have been synthesized and their structure investigated both in the solid state and in solution phase through spectroscopic methods (FT-IR, Mössbauer, 1H and 13C NMR). According to experimental analytical data, the stoichiometry of the complexes has been proposed as R2SnBac2 and R3SnBac, respectively for diorganotin(IV) and triorganotin(IV) baclofen complexes. (Baclofen = HBac; R = Me, Bu, Ph).
PRINZIVALLI C, ABBATE M, CASELLA G, CATALDO S, FIORE T, NAGY L, et al. (2008). Organotin(IV)derivatives neurotoxicity and their modulation by Baclofen. ATTI DELLA ACCADEMIA DI SCIENZE, LETTERE E ARTI DI PALERMO, PARTE PRIMA: SCIENZE, SERIE QUINTA, VOL.XXIV (TOMO I: Scienze), 139-152.
Organotin(IV)derivatives neurotoxicity and their modulation by Baclofen
PRINZIVALLI, Cristina;ABBATE, Michele;CASELLA, Girolamo;CATALDO, Salvatore;FIORE, Tiziana;PELLERITO, Claudia;SCOPELLITI, Michelangelo;PELLERITO, Lorenzo
2008-01-01
Abstract
Several new diorganotin(IV) and triorganotin(IV) complexes with 4-amino-3- (4-chloro phenyl)]-butanoic acid ( = Baclofen) have been synthesized and their structure investigated both in the solid state and in solution phase through spectroscopic methods (FT-IR, Mössbauer, 1H and 13C NMR). According to experimental analytical data, the stoichiometry of the complexes has been proposed as R2SnBac2 and R3SnBac, respectively for diorganotin(IV) and triorganotin(IV) baclofen complexes. (Baclofen = HBac; R = Me, Bu, Ph).
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