Archivio istituzionale della ricerca dell'Università degli Studi di Palermo
IRIS è il sistema di gestione integrata dei dati della ricerca (persone, pubblicazioni, progetti, attività) adottato dall’Università di Palermo, e ha lo scopo di raccogliere, conservare, documentare, e diffondere ad accesso aperto le informazioni relative alla produzione scientifica degli autori afferenti all’Ateneo.
EnglishSamples of ammonium tartrate irradiated with doses of about 0.1–1 kGy by different beams of ionizing radiation (60Co–γ, 19 MeV protons and 62 MeV per nucleon carbon ions) were studied by continuous-wave electron paramagnetic resonance (cw-EPR) and by pulse-EPR techniques. Careful analysis of the cw-EPR and of the echo-detected EPR spectra allowed the identification of a second radical in the system besides the already known radical formed at high temperature by an hydrogen elimination at C(2) position [M. Brustolon et al., Res. Chem. Int 4:359, 1996]. The spectrum of the radical is compatible with that of a radical obtained by hydroxyl elimination.
Brustolon, M., Tampieri, F., Marrale, M., & Barbon, A. (2015). Determination of New Radical Species in Ammonium Tartrate Dosimeters by CW- and Pulsed-EPR Techniques. APPLIED MAGNETIC RESONANCE, 46(4), 481-488 [10.1007/s00723-015-0642-y].
| Data di pubblicazione: | 2015 | |
| Titolo: | Determination of New Radical Species in Ammonium Tartrate Dosimeters by CW- and Pulsed-EPR Techniques | |
| Autori: | ||
| Citazione: | Brustolon, M., Tampieri, F., Marrale, M., & Barbon, A. (2015). Determination of New Radical Species in Ammonium Tartrate Dosimeters by CW- and Pulsed-EPR Techniques. APPLIED MAGNETIC RESONANCE, 46(4), 481-488 [10.1007/s00723-015-0642-y]. | |
| Rivista: | ||
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1007/s00723-015-0642-y | |
| Abstract: | Samples of ammonium tartrate irradiated with doses of about 0.1–1 kGy by different beams of ionizing radiation (60Co–γ, 19 MeV protons and 62 MeV per nucleon carbon ions) were studied by continuous-wave electron paramagnetic resonance (cw-EPR) and by pulse-EPR techniques. Careful analysis of the cw-EPR and of the echo-detected EPR spectra allowed the identification of a second radical in the system besides the already known radical formed at high temperature by an hydrogen elimination at C(2) position [M. Brustolon et al., Res. Chem. Int 4:359, 1996]. The spectrum of the radical is compatible with that of a radical obtained by hydroxyl elimination. | |
| URL: | http://www.springerlink.com/content/0937-9347 | |
| Appare nelle tipologie: | 1.01 Articolo in rivista |
File in questo prodotto:
| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| 2015_AA44_AT_radical_newSpecies.pdf | N/A | Administrator Richiedi una copia |
http://hdl.handle.net/10447/350823
Copyright © 2022