The reaction between bismuthate oxide and phen (1,10-phenanthroline) in acid medium led to the isolation of the unusual [(PhenH)(PhenH2)][BiCl6] 2H2O derivative, which has been characterized by X-ray analysis and IR spectroscopy. The compound crystallizes in the triclinic space group P1 with a = 8.313(2), b = 9.349(2), c = 9.807(3) A, a = 86.39(3), B = 110.27(3) and y = 106.48(3)°. The crystal structure is made of [BiCl6] 3- anions and [(PhenHXPhenr2)]3+cations. A network of hydrogen bond interactions involving the two clathrated water molecules, the phenanthroline moiety and the chlorines characterizes the entire structure.

BENETOLLO, F., BOMBIERI, G., ALONZO, G., BERTAZZI, N., CASELLA, G. (1998). Synthesis and crystal structure of [(PhenH)(PhenH2)][BiCl6] . 2H2O with different o-phenanthroline protonations. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 28(11), 791-796 [10.1023/A:1021871502627].

Synthesis and crystal structure of [(PhenH)(PhenH2)][BiCl6] . 2H2O with different o-phenanthroline protonations.

ALONZO, Giuseppe;BERTAZZI, Nuccio;CASELLA, Girolamo
1998-01-01

Abstract

The reaction between bismuthate oxide and phen (1,10-phenanthroline) in acid medium led to the isolation of the unusual [(PhenH)(PhenH2)][BiCl6] 2H2O derivative, which has been characterized by X-ray analysis and IR spectroscopy. The compound crystallizes in the triclinic space group P1 with a = 8.313(2), b = 9.349(2), c = 9.807(3) A, a = 86.39(3), B = 110.27(3) and y = 106.48(3)°. The crystal structure is made of [BiCl6] 3- anions and [(PhenHXPhenr2)]3+cations. A network of hydrogen bond interactions involving the two clathrated water molecules, the phenanthroline moiety and the chlorines characterizes the entire structure.
1998
BENETOLLO, F., BOMBIERI, G., ALONZO, G., BERTAZZI, N., CASELLA, G. (1998). Synthesis and crystal structure of [(PhenH)(PhenH2)][BiCl6] . 2H2O with different o-phenanthroline protonations. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 28(11), 791-796 [10.1023/A:1021871502627].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10447/34966
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