(Matrix presented) Novel suitably functionalized tetracyanoanthraquinodimethane (TCAQ) derivatives covalently linked to thiophene moieties have been synthesized. The thiophene-based monomers have been chemically polymerized and copolymerized to yield new and soluble donor-acceptor double-cable polymers. The absorption and emission data reveal that the optical properties can be finely tuned by modifying the ratio of monomers in the copolymerization process.
Giacalone, F., Segura, J.L., Martín, N., Catellani, M., Luzzati, S., Lupsac, N. (2003). Synthesis of soluble donor - Acceptor double-cable polymers based on polythiophene and tetracyanoanthraquinodimethane (TCAQ). ORGANIC LETTERS, 5(10), 1669-1672 [10.1021/ol034324e].
Synthesis of soluble donor - Acceptor double-cable polymers based on polythiophene and tetracyanoanthraquinodimethane (TCAQ)
Giacalone, Francesco;
2003-01-01
Abstract
(Matrix presented) Novel suitably functionalized tetracyanoanthraquinodimethane (TCAQ) derivatives covalently linked to thiophene moieties have been synthesized. The thiophene-based monomers have been chemically polymerized and copolymerized to yield new and soluble donor-acceptor double-cable polymers. The absorption and emission data reveal that the optical properties can be finely tuned by modifying the ratio of monomers in the copolymerization process.
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