Time dynamics of doping and strain induced in single layer graphene by thermal treatments up to 300°C in vacuum, nitrogen, carbon dioxide and oxygen controlled atmosphere are deeply studied by Raman spectroscopy and they are compared with its morphological evolution investigated by Atomic Force Microscopy. The reaction dynamics in oxygen treatments is determined down to a time scale of few minutes as well as that of dedoping process made by water vapor treatment. The interplay of strain modification and doping effects is separated. The strain is clarified to be strongly influenced by the cooling time. The doping removal is dominated by the water vapor, showing that the concentration of molecular water in gas phase governs the process rate. The opportune choice of heating/cooling and atmosphere enables to tune selectively the strain or doping.

Armano, A., Buscarino, G., Cannas, M., Gelardi, F., Giannazzo, F., Schilirò, E., et al. (2018). Monolayer graphene doping and strain dynamics induced by thermal treatments in controlled atmosphere. CARBON, 127, 270-279 [10.1016/j.carbon.2017.11.008].

Monolayer graphene doping and strain dynamics induced by thermal treatments in controlled atmosphere

Armano, A.;Buscarino, G.;Cannas, M.;Gelardi, F.;Agnello, S.
2018-01-01

Abstract

Time dynamics of doping and strain induced in single layer graphene by thermal treatments up to 300°C in vacuum, nitrogen, carbon dioxide and oxygen controlled atmosphere are deeply studied by Raman spectroscopy and they are compared with its morphological evolution investigated by Atomic Force Microscopy. The reaction dynamics in oxygen treatments is determined down to a time scale of few minutes as well as that of dedoping process made by water vapor treatment. The interplay of strain modification and doping effects is separated. The strain is clarified to be strongly influenced by the cooling time. The doping removal is dominated by the water vapor, showing that the concentration of molecular water in gas phase governs the process rate. The opportune choice of heating/cooling and atmosphere enables to tune selectively the strain or doping.
2018
Armano, A., Buscarino, G., Cannas, M., Gelardi, F., Giannazzo, F., Schilirò, E., et al. (2018). Monolayer graphene doping and strain dynamics induced by thermal treatments in controlled atmosphere. CARBON, 127, 270-279 [10.1016/j.carbon.2017.11.008].
File in questo prodotto:
File Dimensione Formato  
Carbon-18-127-270-Angelo.pdf

Solo gestori archvio

Descrizione: Articolo e supporting information
Tipologia: Versione Editoriale
Dimensione 4.67 MB
Formato Adobe PDF
4.67 MB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10447/253559
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 27
  • ???jsp.display-item.citation.isi??? 29
social impact