The behaviour of some ortho-alkylhetero-substituted diphenylcarbinols, including deuterium labelled derivatives, under chemical ionisation (methane or isobutane) conditions has been investigated. It has been determined that ortho-alkylhetero diphenylmethyl cations formed by water elimination from the protonated molecule undergo consecutive rearrangements which afford benzyl (or tropylium) ions previously observed for ortho- substituted diphenylcarbenium ions generated by electron ionisation. This reaction also occurs under low-energy collision conditions. Copyright (C) 2000 John Wiley and Sons, Ltd.

Bongiorno, D., Ceraulo, L., Lamartina, L., & Natoli, M. (2000). Studies in organic mass spectrometry. Part 25. Benzyl ion formation in chemical ionisation (methane or isobutane) of some ortho-alkylhetero-substituted diphenylcarbinols. RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 14(4), 203-206.

Studies in organic mass spectrometry. Part 25. Benzyl ion formation in chemical ionisation (methane or isobutane) of some ortho-alkylhetero-substituted diphenylcarbinols

BONGIORNO, David;CERAULO, Leopoldo;LAMARTINA, Liliana;NATOLI, Maria Concetta
2000

Abstract

The behaviour of some ortho-alkylhetero-substituted diphenylcarbinols, including deuterium labelled derivatives, under chemical ionisation (methane or isobutane) conditions has been investigated. It has been determined that ortho-alkylhetero diphenylmethyl cations formed by water elimination from the protonated molecule undergo consecutive rearrangements which afford benzyl (or tropylium) ions previously observed for ortho- substituted diphenylcarbenium ions generated by electron ionisation. This reaction also occurs under low-energy collision conditions. Copyright (C) 2000 John Wiley and Sons, Ltd.
Bongiorno, D., Ceraulo, L., Lamartina, L., & Natoli, M. (2000). Studies in organic mass spectrometry. Part 25. Benzyl ion formation in chemical ionisation (methane or isobutane) of some ortho-alkylhetero-substituted diphenylcarbinols. RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 14(4), 203-206.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10447/243658
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