Two series of fluorine-containing UiO-66 have been synthesized, replacing the 1,4-benzodicarboxylic acid linker with increasing amounts of 2-fluoro-1,4-benzodicarboxylic acid or 2-trifluoromethyl-1,4-benzodicarboxylic acid. The capacity to store oxygen and nitrogen within these MOFs has been tested, which revealed a positive correlation between the fluorine content and the oxygen storage performances.

Piscopo, C., Trapani, F., Polyzoidis, A., Schwarzer, M., Pace, A., Loebbecke, S. (2016). Positive effect of the fluorine moiety on the oxygen storage capacity of UiO-66 metal-organic frameworks. NEW JOURNAL OF CHEMISTRY, 40(10), 8220-8224 [10.1039/c6nj02169g].

Positive effect of the fluorine moiety on the oxygen storage capacity of UiO-66 metal-organic frameworks

PACE, Andrea;
2016-10-01

Abstract

Two series of fluorine-containing UiO-66 have been synthesized, replacing the 1,4-benzodicarboxylic acid linker with increasing amounts of 2-fluoro-1,4-benzodicarboxylic acid or 2-trifluoromethyl-1,4-benzodicarboxylic acid. The capacity to store oxygen and nitrogen within these MOFs has been tested, which revealed a positive correlation between the fluorine content and the oxygen storage performances.
1-ott-2016
Piscopo, C., Trapani, F., Polyzoidis, A., Schwarzer, M., Pace, A., Loebbecke, S. (2016). Positive effect of the fluorine moiety on the oxygen storage capacity of UiO-66 metal-organic frameworks. NEW JOURNAL OF CHEMISTRY, 40(10), 8220-8224 [10.1039/c6nj02169g].
File in questo prodotto:
File Dimensione Formato  
c6nj02169g.pdf

accesso aperto

Descrizione: Articolo Principale
Dimensione 2.29 MB
Formato Adobe PDF
2.29 MB Adobe PDF Visualizza/Apri

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10447/229313
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 35
  • ???jsp.display-item.citation.isi??? 34
social impact