Two series of fluorine-containing UiO-66 have been synthesized, replacing the 1,4-benzodicarboxylic acid linker with increasing amounts of 2-fluoro-1,4-benzodicarboxylic acid or 2-trifluoromethyl-1,4-benzodicarboxylic acid. The capacity to store oxygen and nitrogen within these MOFs has been tested, which revealed a positive correlation between the fluorine content and the oxygen storage performances.
Piscopo, C., Trapani, F., Polyzoidis, A., Schwarzer, M., Pace, A., Loebbecke, S. (2016). Positive effect of the fluorine moiety on the oxygen storage capacity of UiO-66 metal-organic frameworks. NEW JOURNAL OF CHEMISTRY, 40(10), 8220-8224 [10.1039/c6nj02169g].
Positive effect of the fluorine moiety on the oxygen storage capacity of UiO-66 metal-organic frameworks
PACE, Andrea;
2016-10-01
Abstract
Two series of fluorine-containing UiO-66 have been synthesized, replacing the 1,4-benzodicarboxylic acid linker with increasing amounts of 2-fluoro-1,4-benzodicarboxylic acid or 2-trifluoromethyl-1,4-benzodicarboxylic acid. The capacity to store oxygen and nitrogen within these MOFs has been tested, which revealed a positive correlation between the fluorine content and the oxygen storage performances.File | Dimensione | Formato | |
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