—It was found that a mixture of molecular iodine and 4-iodotoluene difluoride are useful to generate in situ the couple IF that was able to add in a Markovnikov fashion and with prevalent anti-stereoselectivity to various alkenes and alkynes.
CONTE P, B PANUNZI, M TINGOLI (2006). Iodofluorination of alkenes and alkynes promoted by iodine and 4-iodotoluene difluoride. TETRAHEDRON LETTERS, 47(3), 273-276 [10.1016/j.tetlet.2005.11.029].
Iodofluorination of alkenes and alkynes promoted by iodine and 4-iodotoluene difluoride
CONTE, Pellegrino;
2006-01-01
Abstract
—It was found that a mixture of molecular iodine and 4-iodotoluene difluoride are useful to generate in situ the couple IF that was able to add in a Markovnikov fashion and with prevalent anti-stereoselectivity to various alkenes and alkynes.
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