A C60-ionic liquid hybrid has been covalently linked to three different solid supports, namely amorphous silica, SBA-15 and Fe2O3@SiO2, and the resulting materials have been employed as covalently supported ionic liquid phases (cSILP) in order to immobilize and stabilize palladium nanoparticles (PdNPs). These novel hybrid materials are based on a sort of "matryoshka" system (PdNPs@imidazolium-salt@C60@support) in which the imidazolium-based moieties have not been directly linked to the surface of the support, but they are present in an octopus-like spatial arrangement on the uniformly surface-distributed fullerenes. These materials have been fully characterized and successfully employed as catalysts in C-C bond forming reactions showing, in the case of Suzuki cross-coupling, an outstanding catalytic activity both under classical heating and by irradiating with microwaves. Turn-over frequencies (TOFs) of up to 3640000 h-1 have been achieved and the silica-based catalyst showed full recyclability even after 10 cycles.

Giacalone, F., Campisciano, V., Calabrese, C., La Parola, V., Liotta, L., Aprile, C., et al. (2016). Supported C60-IL-PdNPs as extremely active nanocatalysts for C-C cross-coupling reactions. JOURNAL OF MATERIALS CHEMISTRY. A, 4(43), 17193-17206 [10.1039/c6ta07599a].

Supported C60-IL-PdNPs as extremely active nanocatalysts for C-C cross-coupling reactions

GIACALONE, Francesco;CAMPISCIANO, Vincenzo;Calabrese, Carla;LA PAROLA, Valeria;LIOTTA, Leonarda Francesca;APRILE, Carmela;GRUTTADAURIA, Michelangelo
2016

Abstract

A C60-ionic liquid hybrid has been covalently linked to three different solid supports, namely amorphous silica, SBA-15 and Fe2O3@SiO2, and the resulting materials have been employed as covalently supported ionic liquid phases (cSILP) in order to immobilize and stabilize palladium nanoparticles (PdNPs). These novel hybrid materials are based on a sort of "matryoshka" system (PdNPs@imidazolium-salt@C60@support) in which the imidazolium-based moieties have not been directly linked to the surface of the support, but they are present in an octopus-like spatial arrangement on the uniformly surface-distributed fullerenes. These materials have been fully characterized and successfully employed as catalysts in C-C bond forming reactions showing, in the case of Suzuki cross-coupling, an outstanding catalytic activity both under classical heating and by irradiating with microwaves. Turn-over frequencies (TOFs) of up to 3640000 h-1 have been achieved and the silica-based catalyst showed full recyclability even after 10 cycles.
Settore CHIM/06 - Chimica Organica
http://pubs.rsc.org/en/journals/journalissues/ta
Giacalone, F., Campisciano, V., Calabrese, C., La Parola, V., Liotta, L., Aprile, C., et al. (2016). Supported C60-IL-PdNPs as extremely active nanocatalysts for C-C cross-coupling reactions. JOURNAL OF MATERIALS CHEMISTRY. A, 4(43), 17193-17206 [10.1039/c6ta07599a].
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10447/212110
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