A facile electrosynthesis route for the preparation of polymer nanogels based on the in situ production of hydroxyl radicals is reported for the first time. Electro-Fenton process with continuous H2O2 electrogeneration and Fe2 + regeneration performs better than electro-oxidation with a boron-doped diamond or dimensionally stable anode for promoting crosslinking of poly(vinylpyrrolidone).
Galia, A., Lanzalaco, S., Sabatino, M., Dispenza, C., Scialdone, O., Sirés, I. (2016). Crosslinking of poly(vinylpyrrolidone) activated by electrogenerated hydroxyl radicals: A first step towards a simple and cheap synthetic route of nanogel vectors. ELECTROCHEMISTRY COMMUNICATIONS, 62, 64-68 [10.1016/j.elecom.2015.12.005].
Crosslinking of poly(vinylpyrrolidone) activated by electrogenerated hydroxyl radicals: A first step towards a simple and cheap synthetic route of nanogel vectors
GALIA, Alessandro;LANZALACO, Sonia;SABATINO, Maria Antonietta;DISPENZA, Clelia;SCIALDONE, Onofrio;
2016-01-01
Abstract
A facile electrosynthesis route for the preparation of polymer nanogels based on the in situ production of hydroxyl radicals is reported for the first time. Electro-Fenton process with continuous H2O2 electrogeneration and Fe2 + regeneration performs better than electro-oxidation with a boron-doped diamond or dimensionally stable anode for promoting crosslinking of poly(vinylpyrrolidone).File | Dimensione | Formato | |
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