The photochemistry of some 3,5-disubstituted 1,2,4-oxadiazoles in the presence of 2,3-dimethyl-2-butene has been investigated. The irradiation in acetonitrile yielded differently substituted N-imidoyl-aziridines through an aziridination reaction involving an acyliminonitrene intermediate. Pyrolysis of N-imidoyl-aziridines produced the corresponding N-allylamidines through a ring opening process.

PALUMBO PICCIONELLO A, PIBIRI I, PACE A, RACCUGLIA RA, BUSCEMI S, VIVONA N, et al. (2007). On the photoreaction of some 1,2,4-oxadiazoles in the presence of 2,3-dimethyl-2-butene. Synthesis of N-imidoylaziridines. HETEROCYCLES, 71(7), 1529-1537 [10.3987/COM-07-11040].

On the photoreaction of some 1,2,4-oxadiazoles in the presence of 2,3-dimethyl-2-butene. Synthesis of N-imidoylaziridines

PALUMBO PICCIONELLO, Antonio;PIBIRI, Ivana;PACE, Andrea;RACCUGLIA, Rosa Angela;BUSCEMI, Silvestre;VIVONA, Nicolo';
2007-01-01

Abstract

The photochemistry of some 3,5-disubstituted 1,2,4-oxadiazoles in the presence of 2,3-dimethyl-2-butene has been investigated. The irradiation in acetonitrile yielded differently substituted N-imidoyl-aziridines through an aziridination reaction involving an acyliminonitrene intermediate. Pyrolysis of N-imidoyl-aziridines produced the corresponding N-allylamidines through a ring opening process.
2007
PALUMBO PICCIONELLO A, PIBIRI I, PACE A, RACCUGLIA RA, BUSCEMI S, VIVONA N, et al. (2007). On the photoreaction of some 1,2,4-oxadiazoles in the presence of 2,3-dimethyl-2-butene. Synthesis of N-imidoylaziridines. HETEROCYCLES, 71(7), 1529-1537 [10.3987/COM-07-11040].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10447/10587
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