Electrochemical deposition of CZTS thin films on flexible substrate

Solar cells based on semiconductor thin films are emerging as alternative to silicon;however,the materials giving the highest efficiency,CdTe and CuInGaSe,contain toxic (Cd) and rare (In) elements.In this field,the challenge is to substitute In and Cd with abundant and non-toxic elements without lowering the high efficiency achieved with these technologies.Compounds based on copper,zinc,tin and sulfur (CZTS) are potentially promising materials,because they present all the above listed features.Among the different methods to obtain CZTS,the electrochemical route appears of great interest because easy to conduct.Up to date,the literature shows that non-uniformity in composition and/or the presence of secondary phases prevent the obtainment of electrochemical CZTS thin-film of high quality.In this paper,we present the principal results of an extensive investigations conducted in order to find suitable conditions for growing CZTS thin films with good performance through the simultaneous electrodeposition of elements having different standard electrochemical potentials.Thin films were obtained on a flexible substrate by potentiostatic deposition from aqueous baths by changing different deposition parameters (bath composition and temperature,deposition time).Chemical composition and structure of the electrodeposited films were evaluated by EDS,SEM,RAMAN and XRD.Preliminary results on the photoelectrochemical behaviour of the films will be also presented.