The preparation of Ce(OH)3/CeO2 nanostructures (NSs) through electrogeneration of base into anodic alumina membranes was studied. The effects of solvent (alcohol and/or water), Ce3? partner anion nature (chloride or nitrate) and concentration, applied potential or current density in driving the morphology toward nanowires (NWs) and/or nanotubes (NTs) was described. The structural analysis performed by X-Ray Diffraction and Raman Spectroscopy allowed to evidence that the presence of Ce(IV) into the nanostructures strongly depends on the oxygen content in the growing environment.

Bocchetta, P., Santamaria, M., Di Quarto, F. (2009). From ceria nanotubes to nanowires through electrogeneration of base. JOURNAL OF APPLIED ELECTROCHEMISTRY, 39, 2073-2081.

From ceria nanotubes to nanowires through electrogeneration of base

SANTAMARIA, Monica;DI QUARTO, Francesco
2009-01-01

Abstract

The preparation of Ce(OH)3/CeO2 nanostructures (NSs) through electrogeneration of base into anodic alumina membranes was studied. The effects of solvent (alcohol and/or water), Ce3? partner anion nature (chloride or nitrate) and concentration, applied potential or current density in driving the morphology toward nanowires (NWs) and/or nanotubes (NTs) was described. The structural analysis performed by X-Ray Diffraction and Raman Spectroscopy allowed to evidence that the presence of Ce(IV) into the nanostructures strongly depends on the oxygen content in the growing environment.
2009
Settore ING-IND/23 - Chimica Fisica Applicata
Bocchetta, P., Santamaria, M., Di Quarto, F. (2009). From ceria nanotubes to nanowires through electrogeneration of base. JOURNAL OF APPLIED ELECTROCHEMISTRY, 39, 2073-2081.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10447/57721
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