Hydrolysis and polycondensation of the coupling agent (aminopropyl) triethoxysilane (APS), axially coordinated to the redox-active complex [Rh 2(form)2(CH3COO)2-(APS) 2], lead to the insertion of redox-active inorganic microdomains into a siloxane network; the new polymers undergo cyclic redox reactions indicating that dirhodium(II,II) centres retain their redox activity even when incorporated into siloxane networks.

LO SCHIAVO S, FORTE C, PIGNATARO B, TRESOLDI G, PIRAINO P (2004). Redox materials by covalent entrapment of redox-active dirhodium(II,II) species in a siloxane network. MACROMOLECULAR RAPID COMMUNICATIONS, 25(10), 1033-1037 [10.1002/marc.200400033].

Redox materials by covalent entrapment of redox-active dirhodium(II,II) species in a siloxane network

PIGNATARO, Bruno Giuseppe;
2004-01-01

Abstract

Hydrolysis and polycondensation of the coupling agent (aminopropyl) triethoxysilane (APS), axially coordinated to the redox-active complex [Rh 2(form)2(CH3COO)2-(APS) 2], lead to the insertion of redox-active inorganic microdomains into a siloxane network; the new polymers undergo cyclic redox reactions indicating that dirhodium(II,II) centres retain their redox activity even when incorporated into siloxane networks.
2004
LO SCHIAVO S, FORTE C, PIGNATARO B, TRESOLDI G, PIRAINO P (2004). Redox materials by covalent entrapment of redox-active dirhodium(II,II) species in a siloxane network. MACROMOLECULAR RAPID COMMUNICATIONS, 25(10), 1033-1037 [10.1002/marc.200400033].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10447/22974
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